Tantalum nitride films integrated with transparent conductive oxide substrates via atomic layer deposition for photoelectrochemical water splitting

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Tantalum nitride films integrated with transparent conductive oxide substrates via atomic layer deposition for photoelectrochemical water splitting.

Tantalum nitride, Ta3N5, is one of the most promising materials for solar energy driven water oxidation. One significant challenge of this material is the high temperature and long duration of ammonolysis previously required to synthesize it, which has so far prevented the use of transparent conductive oxide (TCO) substrates to be used which would allow sub-bandgap light to be transmitted to a ...

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Tantalum nitride films integrated with transparent conductive oxide substrates via atomic layer deposition for photoelectrochemical water splitting† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6sc02116f Click here for additional data file.

Figure S1. EDS spectrum of Ta-doped TiO2 as a function of ratio of cycles of TaOx to TiO2, a) 1:150, b) 1:100, and c) 1:50. d) Atomic percentage of Ta as a function of ratio of cycles of TaOx:TiO2.

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Correction: Enhanced photoelectrochemical water oxidation via atomic layer deposition of TiO2 on fluorine-doped tin oxide nanoparticle films.

Correction for 'Enhanced photoelectrochemical water oxidation via atomic layer deposition of TiO2 on fluorine-doped tin oxide nanoparticle films' by Isvar A. Cordova, et al., Nanoscale, 2015, 7, 8584-8592.

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Enhanced photoelectrochemical water oxidation via atomic layer deposition of TiO2 on fluorine-doped tin oxide nanoparticle films.

TiO2 is an exemplary semiconductor anode material for photoelectrochemical (PEC) water-splitting electrodes due to its functionality, long-term stability in corrosive environments, nontoxicity, and low cost. In this study, TiO2 photoanodes with enhanced photocurrent density were synthesized by atomic layer deposition (ALD) of TiO2 onto a porous, transparent, and conductive fluorine-doped tin ox...

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Transparent Conductive Oxide Thin Films

Transparent conductive oxides (TCO) have high optical transmission at visible wavelengths and electrical conductivity close to that of metals. They also reflect near infrared and infrared (i.e., heat) wavelengths, and are used in products ranging from energy efficient low-e windows to photovoltaics. One of their most important uses is for transparent electrical contacts. Virtually all applicati...

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ژورنال

عنوان ژورنال: Chemical Science

سال: 2016

ISSN: 2041-6520,2041-6539

DOI: 10.1039/c6sc02116f